Repeat if the scarf still feels stiff. Old scarves tend to go stiff over time.
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I recommend hand washing wool or cashmere scarves rather than machine washing:

How to wash silk scarf vinegar. Mix well so that the soap is well distributed in the water. Consequently, you can use this tip to restore some of the sheen, shine, and softness of your silk scarf. How to wash a silk scarf.
Rinse it with warm water to move all soap residues. You then dry it by pressing it between two towels. I) open the scarf out into the final rinse bath of cold water, swish it about a couple of times, then lift it out by the two top corners and lay it out flat on the towel.
Repeat on the other side of the scarf and immediately put the scarf into the bath. This will neutralize alkali traces, dissolve soap residue and ultimately keep the silk shiny. How to make your silk scarf last
Although most silk garments are labeled dry clean only, you can wash 100 percent silk fabric at home with gentle products and special care. Soak the silk in the mixture for several hours, occasionally swishing the silk fabric around in the water. Next, add distilled white vinegar to the rinse water.
Finally, spread the scarf out on a. Roll it up to absorb the water; Rinse well so that no traces of soap are left on the fabric.
How to hand wash silk scarves. Remove the scarf from the vinegar water, and rinse several times in clean water. Gently swish and swirl the scarf around your sink.
After five minutes, drain the water from the bowl and refill with cool water and cup of white vinegar. (dont let the scarf stand in the water, for the color may be transferred.) gently squeeze excess water. Do not wring the scarf.
Once you submerge your scarf, you have to keep it moving for the entire 4 minutes. After rinsing, fill the sink with more lukewarm water and add one tablespoon of white vinegar. Rinse the scarf in cool, clean water.
Remove stains from vinegar silk with white vinegar. If you find a minor tear, you should gently cut off any loose ends before bringing the material together and sewing it shut using a threat of the same colour as the scarf. Avoid wringing or squeezing the scarf in the water.
You can fix a loss of lustre in your silk scarf by washing it in a mix of vinegar and warm water. Submerge your item and gently agitate the water with your hand to evenly distribute soap and water. Fill a sink or bowl with warm water and a teaspoon of very mild detergent.
Washing wool and cashmere scarves. Do not ring to the silk, as this can damage the fibers. Roll, swish and move it about for a full five minutes.
Before you start do a test to see if the shampoo will damage the fabric. Submerge the scarf, and swish it around to soak. Select a cool, delicate cycle (do not set the wash temperature to any higher than 30c).
Silk can turn yellow for various reasons, such as exposure to perspiration, extended storage time and improper cleaning methods. Soak the silk in a bowl of lukewarm water mixed with several drops of soap (something gentle like simple kind to skin pure handwash will be best) for no longer than five minutes. The movement also ensures that each area of your scarf is.
Spread the scarf on a heavy, clean white towel; Submerge sponge into the mixture. Take a mix of 60ml distilled vinegar and 2 liters of warm water.
Then, soak the scarf in the mix and let it absorb the vinegar water. Run cool water through items until rinse water is no longer soapy. Were now ready to put our silk scarf in the water.
Place the scarf in the sink. Then rinse with cold water until the water runs clear. Dip your silk piece into the vinegar cleaning solution.
Be careful to pay more attention to the dirtier spots. Its important only to wash one silk scarf at a time. Rinse then add a little vinegar to the rinse water to remove any soap residue.
Leave the scarf to soak for around 5 mins, gently swirling it from time to time. Soak for up to 30 minutes. Once the soap and vinegar is completely rinsed away, squeeze the fabric softly to remove excess water.
Handwash very carefully using baby shampoo and cold water. J) roll them up into a sausage. Rinse the scarf in clean water a few times.
Submerge the entire piece so all the stains make contact with the solution. Use a cold water and a wool/cashmere friendly detergent. Apply a small amount of liquid dishwashing detergent into a sink with tepid water.
To a washbasin or sink filled with cool water. Repeat until most of the water is absorbed; Wash the entire scarf instead.
Dip a cotton bud into the solution and lightly rub on the spot. Dilute a few teaspoons of vinegar in a cup of water. The danger that comes with silk scarves is that the fabric may snag on you as you wash it.
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